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Sperm oil
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Sperm oil (see also: ) is a waxy liquid obtained from . It is a clear, yellowish liquid with a very faint odor. Sperm oil has a different composition from common , obtained from rendered . Although it is traditionally called an "oil", it is technically a liquid wax. It is composed of with a small proportion of , an of an unsaturated fatty acid, and a branched-chain . It is a natural and heat transfer agent. In the late-18th and early-19th centuries, sperm oil was prized as an illuminant for its bright, odorless flame and as a for its low and stability. It was supplanted in the late 19th century by less expensive alternatives such as and -based lubricants. With the 1987 international ban on whaling, sperm oil is no longer legally sold.

The oil from was sometimes called "Arctic sperm oil." It was cheaper than but inferior to true sperm oil.


Processing
After killing a sperm whale, the whalers would pull the carcass alongside the ship, cut off the cranium and haul it on deck, whereupon they would cut a hole in it and bail out the matter inside with a bucket. The primary source of sperm oil was the and the junk (or "melon"), the organs that serve to focus and modulate the animal's vocalizations. The matter from these organs was stored in casks to be processed on land; sometimes it was boiled first to prevent it going rancid. The blubber also contained smaller proportions of spermaceti, which was obtained by boiling the blubber on the ship itself.

On land, the casks of head-matter were allowed to chill during the winter, causing it to congeal into a spongy and viscous mass. The congealed matter was then loaded into wool sacks and placed in a press to squeeze out its liquid. This liquid was bottled and sold as "winter-strained sperm oil". This was the most valuable product: a lubricant that remained liquid in freezing winter temperatures. When spring came and the leftover solid matter melted a bit, the liquid was strained off and sold as "spring-strained sperm oil". In summer, the matter melted some more and the liquid was strained off to leave a fully solid wax. This wax, brown in color, was then bleached and sold as "spermaceti wax". Wilson Heflin (2004). Herman Melville's Whaling Years. pg 232


Chemistry
+ Physical properties of sperm oil
0.884 at 15.6 °C Emil F. Dieterichs (1916). A Practical Treatise On Friction, Lubrication, Fats And Oils. pg 22
260–266 °C Richard P. Pohanish (2005). HazMat Data: For First Response, Transportation, Storage, and Security. pg 865
120–150.3 Moninder Mohan Chakrabarty (2009). Chemistry And Technology Of Oils And Fats. pg 183
17.5–44.0%
1.4649 at 15.6 °C[https://archive.org/stream/tablesofrefracti00goldrich#page/n241/mode/2up J. N. Goldsmith (1921). ''Table of Refractive Indices''. pg 239]
(Wijs)
70.4–96.4
21–23 cSt at 37.5 °C
180
Sperm oil has a fairly low viscosity (roughly equal to ). It retains its viscosity in high temperatures better than most oils. It does not tend to become rancid, dry out, or corrode metals. Sperm oil cannot be easily , and thus could not be used to make soap or .
(1984). 9780520039735, University of California Press. .
(1988). 9780774843157, UBC Press. .
It is fairly resistant to oxidization.
(1990). 9780080875798, Elsevier. .

is a liquid wax, composed mostly of (chiefly ) and a smaller proportion of , with being the most common . The proportion of wax esters in the spermaceti organ increases with the age of the whale: 38-51% in calves, 58-87% in adult females, and 71-94% in adult males. The blubber oil of the whale is about 66% wax.William F. Perrin, Bernd Würsig, J. G. M. Thewissen (2002). Encyclopedia of Marine Mammals. pg 1164 When cooled to below , the waxes in spermaceti begin to crystallize.

Winter-strained sperm oil is roughly two-thirds wax esters and one third triglycerides. Most of the carbon chains are unsaturated, with 18:1 being the most common. Unlike other toothed whales save the Amazon river dolphin, most of the carbon chains in the wax esters are relatively long (C10-C22).


Applications
Sperm oil was particularly prized as an illuminant in oil lamps, as it burned more brightly and cleanly than any other available oil and gave off no foul odor. It was replaced in the late-19th century by cheaper, more efficient .

In the US, sperm oil was used in cars as an additive to automatic transmission fluid until it was banned by the Endangered Species Act. It was also a major component of in (like the ubiquitous JDM Type 303 Special Hydraulic Fluid) until its withdrawal in 1974." The Yellow Bucket", Thomas Glenn, Lubes N' Greases, LND Publishing Co., Inc., February 2012, Vol. 18, No. 2, p.12.

Prior to 1972, over of sperm whale oil was used annually in lubricants because of its exceptional lubricity and heat stability.Landis, Phil. Gears for the Transmission Rebuilding Industry. Oxnard: Automatic Transmission Rebuilders Association, 2010. Print. In 1972, the sperm whale was listed as an Endangered Species. The following year, the US Congress amended the Endangered Species Act, outlawing the killing of whales and the use of their oil. The loss of sperm oil had a profound impact in the automotive industry, where for example, transmission failures rose from under 1 million in 1972 to over 8 million by 1975.

Sperm oil was a popular lubricant. It worked well for fine, light machinery such as sewing machines and watches because it is thin, does not congeal or dry out and does not corrode metals. It was also used in heavy machinery such as locomotives and steam-powered looms because it can withstand high temperatures.: Paul Lucier, Scientists and Swindlers (2008). Consulting on Coal and Oil in America. pg 152. In the late 20th century, was discovered to be a better substitute for high-friction applications because it is even more stable at high temperatures. This caused sperm oil's price to collapse to a tenth of its previous value.James R. McGuigan, R. Charles Moyer, Frederick H. deB Harris (2010). Managerial Economics, pg 29.

Because of its very low , sperm oil saw widespread use in the aerospace industry. American Whaling, New Bedford Whaling Museum. Modified August 22, 2014.

Sperm oil was used to protect metals from rust. A coat of sperm oil provided a temporary protection for the metal components in firearms, because it did not dry out or gum up.Roy F. Dunlap (1963). Gunsmithing: The complete sourcebook of firearms design, construction, alteration, and restoration for amateur and professional gunsmiths. pg= 84.William S. Brophy (1985). The Springfield 1903 Rifles. pg 71. It was the basis of the original (but not current) .

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